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  Cine-Substitutions at Five-Membered Hetarenes Enabled by Sulfonium Salts

Berger, F., Alvarez, E. M., Frank, N., Bohdan, K., Kondratiuk, M., Torkowski, L., et al. (2020). Cine-Substitutions at Five-Membered Hetarenes Enabled by Sulfonium Salts. Organic Letters, 22(14), 5671-5674. doi:10.1021/acs.orglett.0c02067.

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 Creators:
Berger, Florian1, Author           
Alvarez, Eva Maria1, Author           
Frank, Nils1, Author
Bohdan, Kostiantyn1, Author           
Kondratiuk, Mykhailo1, Author           
Torkowski, Luca1, Author           
Engl, Pascal S.1, Author           
Barletta, Joana1, Author
Ritter, Tobias1, Author           
Affiliations:
1Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040308              

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 Abstract: We report a nucleophilic substitution reaction of five-membered hetarylsulfonium salts that results in a change of the substitution pattern on the arene. The products of these cine-substitutions are hard to access synthetically otherwise. The sulfonium salts that serve as starting materials are generated by a highly site-selective C–H functionalization reaction.

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Language(s): eng - English
 Dates: 2020-06-232020-07-082020-07-17
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/acs.orglett.0c02067
 Degree: -

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Title: Organic Letters
  Other : Org. Lett.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 22 (14) Sequence Number: - Start / End Page: 5671 - 5674 Identifier: ISSN: 1523-7060
CoNE: https://pure.mpg.de/cone/journals/resource/954925626338