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  Continuous heterogeneous photocatalysis in serial micro-batch reactors

Pieber, B., Shalom, M., Antonietti, M., Seeberger, P. H., & Gilmore, K. (2018). Continuous heterogeneous photocatalysis in serial micro-batch reactors. Angewandte Chemie International Edition, 57(31), 9976-9979. doi:10.1002/anie.201712568.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0006-D991-1 Version Permalink: http://hdl.handle.net/21.11116/0000-0006-ED7D-4
Genre: Journal Article
Other : Kontinuierliche heterogene Photokatalyse in seriellen Mikro‐Batch‐Reaktoren

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 Creators:
Pieber, Bartholomäus1, Author              
Shalom, Menny2, Author              
Antonietti, Markus3, Author              
Seeberger, Peter H.4, Author              
Gilmore, Kerry5, Author              
Affiliations:
1Bartholomäus Pieber, Biomolekulare Systeme, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2522692              
2Menny Shalom, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2205635              
3Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              
4Peter H. Seeberger - Automated Systems, Biomolekulare Systeme, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863306              
5Kerry Gilmore, Biomolekulare Systeme, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863304              

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Free keywords: carbon nitrides, flow chemistry, fluorination, heterogeneous catalysis, photocatalysis
 Abstract: Abstract Solid reagents, leaching catalysts, and heterogeneous photocatalysts are commonly employed in batch processes but are ill-suited for continuous-flow chemistry. Heterogeneous catalysts for thermal reactions are typically used in packed-bed reactors, which cannot be penetrated by light and thus are not suitable for photocatalytic reactions involving solids. We demonstrate that serial micro-batch reactors (SMBRs) allow for the continuous utilization of solid materials together with liquids and gases in flow. This technology was utilized to develop selective and efficient fluorination reactions using a modified graphitic carbon nitride heterogeneous catalyst instead of costly homogeneous metal polypyridyl complexes. The merger of this inexpensive, recyclable catalyst and the SMBR approach enables sustainable and scalable photocatalysis.

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Language(s): eng - English
 Dates: 2018-01-292018
 Publication Status: Published in print
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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 57 (31) Sequence Number: - Start / End Page: 9976 - 9979 Identifier: ISSN: 1433-7851

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Title: Angewandte Chemie
  Abbreviation : Angew. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 130 (31) Sequence Number: - Start / End Page: 10127 - 10131 Identifier: ISSN: 0044-8249