English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  5-Hydroxymethylfurfural hydrodeoxygenation to 2,5-dimethylfuran in continuous-flow system over Ni on nitrogen-doped carbon

Brandi, F., Bäumel, M., Shekova, I., Molinari, V., & Al-Naji, M. (2020). 5-Hydroxymethylfurfural hydrodeoxygenation to 2,5-dimethylfuran in continuous-flow system over Ni on nitrogen-doped carbon. Sustainable Chemistry, 1(2), 106-115. doi:10.3390/suschem1020009.

Item is

Files

show Files
hide Files
:
Article.pdf (Publisher version), 391KB
Name:
Article.pdf
Description:
-
OA-Status:
Gold
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
-
Copyright Info:
-

Locators

show

Creators

show
hide
 Creators:
Brandi, Francesco1, Author           
Bäumel, Marius1, Author           
Shekova, Irina2, Author           
Molinari, Valerio3, Author           
Al-Naji, Majd1, Author           
Affiliations:
1Majd Al-Naji, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_3050472              
2Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863288              
3Valerio Molinari, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2385693              

Content

show
hide
Free keywords: biomass; 5-hydroxymethylfurfural; 2,5-dimethylfyran; nitrogen-doped carbon; continuous flow system; nickel
 Abstract: Waste lignocellulosic biomass is sustainable and an alternative feedstock to fossil resources. Among the lignocellulosic derived compounds, 2,5-dimethylfuran (DMF) is a promising building block for chemicals, e.g., p-xylene, and a valuable biofuel. DMF can be obtained from 5-hydroxymethylfurfural (HMF) via catalytic deoxygenation using non-noble metals such as Ni in the presence of H2. Herein, we present the synthesis of DMF from HMF using 35 wt. Ni on nitrogen-doped carbon pellets (35Ni/NDC) as a catalyst in a continuous flow system. The conversion of HMF to DMF was studied at different hydrogen pressures, reaction temperatures, and space times. At the best reaction conditions, i.e., 423 K, 8.0 MPa, and space time 6.4 kgNi h kgHMF-1, the 35Ni/NDC catalyst exhibited high catalytic activity with HMF conversion of 99 mol and 80 mol of DMF. These findings can potentially contribute to the transition toward the production of sustainable fine chemicals and liquid transportation fuels.

Details

show
hide
Language(s):
 Dates: 2020-08-192020
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.3390/suschem1020009
BibTex Citekey: suschem1020009
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Sustainable Chemistry
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Basel : MDPI
Pages: - Volume / Issue: 1 (2) Sequence Number: - Start / End Page: 106 - 115 Identifier: ISSN: 2673-4079