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  Characterization of silver-rich ternary oxides with photoelectron spectroscopy

Heidebrecht, K., Jansen, M., Krause, S., & Bradshaw, A. M. (1990). Characterization of silver-rich ternary oxides with photoelectron spectroscopy. Journal of Solid State Chemistry, 89(1), 60-66. doi:10.1016/0022-4596(90)90293-7.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0006-F664-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0006-F665-3
Genre: Journal Article

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 Creators:
Heidebrecht, K1, Author
Jansen, Martin1, Author
Krause, Siegfried2, Author           
Bradshaw, Alexander M.2, Author           
Affiliations:
1Anorganisch-Chemisches Institute der Universität Bonn, Gerhard-Domagk-Strasse 1, 5300 Bonn, Federal Republic of Germany, ou_persistent22              
2Fritz Haber Institute, Max Planck Society, ou_24021              

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 Abstract: The silver-rich ternary oxides Ag6Si2O7, Ag10Si4O13, Ag6Ge2O7, and Ag10Ge4O13, as well as Ag2SO4, have been investigated with photoelectron spectroscopy. The Ag 3d core level binding energies in all four ternary oxides were found to be identical with that of Ag metal, compared to the small negative chemical shift observed in AgSO4 and most other silver compounds. The MgKα and HeI valence band spectra are both dominated by Ag 4d emission; at the lower photon energy O 2p-derived states are also observed. There is some evidence for a direct Ag 4d-O 2p interaction.

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Language(s): eng - English
 Dates: 1990-03-121990-11
 Publication Status: Issued
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0022-4596(90)90293-7
 Degree: -

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Title: Journal of Solid State Chemistry
Source Genre: Journal
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Publ. Info: Orlando, Fla. : Academic Press
Pages: 7 Volume / Issue: 89 (1) Sequence Number: - Start / End Page: 60 - 66 Identifier: ISSN: 0022-4596
CoNE: https://pure.mpg.de/cone/journals/resource/954922646045