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  The dehydrogenation of cyclohexane on Pt(100): the role of surface structure in determining the reaction pathway

Martin, R., Gardner, P., Tüshaus, M., Bonev, C., Bradshaw, A. M., & Jones, T. S. (1990). The dehydrogenation of cyclohexane on Pt(100): the role of surface structure in determining the reaction pathway. Journal of Electron Spectroscopy and Related Phenomena, 54-55, 773-778. doi:10.1016/0368-2048(90)80269-G.

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 Creators:
Martin, Rachel1, Author           
Gardner, Peter1, Author           
Tüshaus, M.1, Author           
Bonev, C.1, Author           
Bradshaw, Alexander M.1, Author           
Jones, T. S.2, Author
Affiliations:
1Fritz Haber Institute, Max Planck Society, ou_24021              
2Surface Science Research Centre, University of Liverpool, Liverpool L69 3BX, England, ou_persistent22              

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 Abstract: Cyclohexane, adsorbed at low temperature on the reconstructed (hex) phase surface of Pt100, shows a softened C-H mode and dehydrogenates to benzene on warming, in the same way as on the Pt111 surface. On the (1×1), or “truncated bulk”, surface of Pt100, however, the spectrum of the chemisorbed layer is more complex, there is no softened mode and dehydrogenation to benzene does not take place. Instead, there is conversion to an as yet unidentified hydrocarbon species, characterised by a single, sharp band at 2948 cm−1.

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Language(s): eng - English
 Dates: 1990
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0368-2048(90)80269-G
 Degree: -

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Title: Journal of Electron Spectroscopy and Related Phenomena
  Abbreviation : J. Electron Spectrosc. Relat. Phenom.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Amsterdam : Elsevier B.V.
Pages: 6 Volume / Issue: 54-55 Sequence Number: - Start / End Page: 773 - 778 Identifier: ISSN: 0368-2048
CoNE: https://pure.mpg.de/cone/journals/resource/954925524767