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  Interaction of CO and NO with WC(0001)

Brillo, J., Sur, R., Kuhlenbeck, H., & Freund, H.-J. (1998). Interaction of CO and NO with WC(0001). Surface Science, 397(1-3), 137-144. doi:10.1016/S0039-6028(97)00725-5.

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 Creators:
Brillo, Jürgen1, Author           
Sur, R.2, Author
Kuhlenbeck, Helmut1, Author           
Freund, Hans-Joachim1, Author           
Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              
2Fritz Haber Institute, Max Planck Society, Faradayweg 4-6, 14195 Berlin, DE, ou_24021              

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 Abstract: The results of angular resolved photoemission and thermal desorption spectroscopy investigations of the adsorption of CO and NO on a WC(0001) single crystal surface are reported. Both molecules are stable only at low temperature. Similar to the case of adsorption on many transition metals, CO is co-ordinated to the surface via its carbon end, standing upright on the surface. Upon warming up, complete dissociation takes place at temperatures of ca 270 K for CO and 160 K for NO. A part of the CO molecules also desorbs between 200 and 250 K, whereas no molecular desorption is found for NO. Recombinative/reactive desorption is observed in the temperature range between 700 and 1200 K.

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Language(s): eng - English
 Dates: 1997-09-111998-02
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0039-6028(97)00725-5
 Degree: -

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Title: Surface Science
  Abbreviation : Surf. Sci.
Source Genre: Journal
 Creator(s):
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Publ. Info: Amsterdam : Elsevier
Pages: 8 Volume / Issue: 397 (1-3) Sequence Number: - Start / End Page: 137 - 144 Identifier: ISSN: 0039-6028
CoNE: https://pure.mpg.de/cone/journals/resource/0039-6028