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  Nickel(II) Phosphane‐ and N‐heterocyclic Carbene Complexes with Tridentate, Dianionic [S,N,O]2– Ligands

Koch, L., Rust, J., Lehmann, C. W., & Mohr, F. (2020). Nickel(II) Phosphane‐ and N‐heterocyclic Carbene Complexes with Tridentate, Dianionic [S,N,O]2– Ligands. Zeitschrift für anorganische und allgemeine Chemie, 646(10), 469-474. doi:10.1002/zaac.202000130.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-2EBE-1 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-2EBF-0
Genre: Journal Article

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 Creators:
Koch, Lena1, Author
Rust, Jörg2, Author           
Lehmann, Christian W.2, Author           
Mohr, Fabian1, Author
Affiliations:
1Anorganische Chemie, Fakultät für Mathematik und Naturwissenschaften, Bergische Universität Wuppertal, Gaußstr. 20, 42119 Wuppertal, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: Tridentate dianionic ligands; Nickel; N-heterocyclic carbene complexes; X-ray structure
 Abstract: Square‐planar dinuclear nickel(II) complexes containing [S,N,O]2– ligands formed by condensation of acetyl acetone or benzoyl acetone with cysteamine were prepared. These dimeric nickel(II) compounds undergo bridge‐cleavage reactions with the cage phosphine PTA (PTA = 1,3,5‐triaza‐7‐phosphaadamantane) or in situ generated N‐heterocyclic carbenes. The resulting diamagnetic, square planar NiII complexes were characterized by spectroscopic methods and X‐ray diffraction.

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Language(s): eng - English
 Dates: 2020-03-162020-05-272020-05-29
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/zaac.202000130
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 646 (10) Sequence Number: - Start / End Page: 469 - 474 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895