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  A Main‐Group Analogue of Housene: The Subtle Influence of the Inert‐Pair Effect in Group 15 Clusters

Fish, C., Green, M., Jeffery, J. C., Kilby, R. J., Lynam, J. M., McGrady, J. E., et al. (2006). A Main‐Group Analogue of Housene: The Subtle Influence of the Inert‐Pair Effect in Group 15 Clusters. Angewandte Chemie International Edition, 45(40), 6685-6689. doi:10.1002/anie.200601804.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-3050-8 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-3051-7
Genre: Journal Article

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 Creators:
Fish, Cheryl1, Author
Green, Michael1, Author
Jeffery, John C.1, Author
Kilby, Richard J.1, Author
Lynam, Jason M.2, Author
McGrady, John E.3, Author
Pantazis, Dimitrios A.3, Author           
Russell, Christopher A.1, Author
Willans, Charlotte E.2, Author
Affiliations:
1School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK, ou_persistent22              
2Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK, ou_persistent22              
3WestCHEM, Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, U. K., ou_persistent22              

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Free keywords: antimony; cluster compounds; density functioal calculations; phosphorus; structure elucidation
 Abstract: The carbon–phosphorus–antimony cage of P2C2tBu2SbCl (see picture) adopts an envelope‐type structure which is quite distinct from its phosphorus analogue, the tricyclic compound P2C2tBu2PCl. DFT calculations reveal that subtle changes in electronic structure as a result of the inert‐pair effect lead to profound differences in structural and dynamic behavior.

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Language(s): eng - English
 Dates: 2006-10-102006-10-13
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200601804
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 45 (40) Sequence Number: - Start / End Page: 6685 - 6689 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851