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  Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium–Phosphorus Double Bond

Derrah, E. J., Pantazis, D. A., McDonald, R., & Rosenberg, L. (2020). Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium–Phosphorus Double Bond. Angewandte Chemie International Edition, 49(19), 3367-3370. doi:10.1002/anie.201000356.

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Genre: Journal Article

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 Creators:
Derrah, Eric J.1, Author
Pantazis, Dimitrios A.2, Author              
McDonald, Robert3, Author
Rosenberg, Lisa1, Author
Affiliations:
1Department of Chemistry, University of Victoria, P.O. Box 3065, Victoria, BC V8W3V6 (Canada), ou_persistent22              
2Institut für Physikalische und Theoretische Chemie, Universität Bonn, Wegelerstrasse 12, D-53115 Bonn, Germany, ou_persistent22              
3X‐ray Crystallography Laboratory, Department of Chemistry, University of Alberta, Edmonton, AB T6G 2G2 (Canada), ou_persistent22              

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Free keywords: alkenes; cycloadditions; metallacycles; P ligands; ruthenium
 Abstract: A square deal for Ru=PR2: The Ru=PR2 π bond in a terminal phosphido complex undergoes regio‐ and stereoselective [2+2] cycloaddition reactions of alkenes to yield metallaphosphacyclobutanes (see structure; P red, Ru yellow, C gray), which are analogous to olefin metathesis intermediates.

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Language(s): eng - English
 Dates: 2020-04-202020-04-26
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201000356
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 49 (19) Sequence Number: - Start / End Page: 3367 - 3370 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851