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  Metal promoted conversion of aromatic amines to ortho-phenylenediimine derivatives by a radical coupling path

Dutta, D., Kundu, S., Weyhermüller, T., & Ghosh, P. (2020). Metal promoted conversion of aromatic amines to ortho-phenylenediimine derivatives by a radical coupling path. Dalton Transactions, 49(16), 5015-5019. doi:10.1039/d0dt00089b.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-A48C-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-A48D-1
Genre: Journal Article

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 Creators:
Dutta, Debarpan1, Author
Kundu, Suman1, Author
Weyhermüller, Thomas2, Author           
Ghosh, Prasanta1, Author
Affiliations:
1external, ou_persistent22              
2Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023871              

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 Abstract: A radical path for the conversion of o-substituted arylamines to o-phenylenediimine derivatives is reported. In the presence of [Ru-II(PPh3)(3)Cl-2] (Ru-P), 2-(phenylthio)aniline ((LH2)-H-SN) acts as an o-amination agent. Reaction of (LH2)-H-SN with Ru-P in toluene promotes (4e + 4H(+)) oxidative dimerization affording an o-phenylenediimine complex of ruthenium(ii). Similarly, intermolecular coupling between (LH2)-H-SN and other arylamines has been achieved.

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Language(s): eng - English
 Dates: 2020
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: ISI: 000530357500003
DOI: 10.1039/d0dt00089b
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Title: Dalton Transactions
  Abbreviation : Dalton Trans.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 49 (16) Sequence Number: - Start / End Page: 5015 - 5019 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323