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キーワード:
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要旨:
Herein, we report the synthesis, characterization, and catalytic performance of cationic Pd(II)-Anthraphos complexes in the intermolecular hydroamination of aromatic alkynes with aromatic amines. The reaction proceeds with 0.18 mol % of catalyst loading, at 90 degrees C for 4 h under neat conditions. Good to excellent yields could be obtained for a broad range of amines and alkynes.