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  Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)-Anthraphos Complexes

Erken, C., Hindemith, C., Weyhermüller, T., Hölscher, M., Werlé, C., & Leitner, W. (2020). Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)-Anthraphos Complexes. ACS Omega, 5(15), 8912-8918. doi:10.1021/acsomega.0c00562.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-A49D-F Version Permalink: https://hdl.handle.net/21.11116/0000-0007-A49E-E
Genre: Journal Article

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 Creators:
Erken, Christina1, Author           
Hindemith, Carsten2, Author           
Weyhermüller, Thomas3, Author           
Hölscher, Markus4, Author
Werlé, Christophe2, Author           
Leitner, Walter1, 5, Author           
Affiliations:
1Research Department Leitner, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023872              
2Research Department Schlögl, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023874              
3Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023871              
4external, ou_persistent22              
5Institut für Technische Chemie und Makromolekulare Chemie, Rheinisch‐Westfälische Technische Hochschule Aachen, Worringer Weg 1, 52074 Aachen, Germany, ou_persistent22              

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 Abstract: Herein, we report the synthesis, characterization, and catalytic performance of cationic Pd(II)-Anthraphos complexes in the intermolecular hydroamination of aromatic alkynes with aromatic amines. The reaction proceeds with 0.18 mol % of catalyst loading, at 90 degrees C for 4 h under neat conditions. Good to excellent yields could be obtained for a broad range of amines and alkynes.

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Language(s): eng - English
 Dates: 2020
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: ISI: 000527748400022
DOI: 10.1021/acsomega.0c00562
 Degree: -

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Title: ACS Omega
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 5 (15) Sequence Number: - Start / End Page: 8912 - 8918 Identifier: ISSN: 2470-1343
CoNE: https://pure.mpg.de/cone/journals/resource/2470-1343