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  A metastable Ru(III)azido complex with metallo-Staudinger reactivity

Park V, S., Fry, C. G., Bill, E., & Berry, J. F. (2020). A metastable Ru(III)azido complex with metallo-Staudinger reactivity. Chemical Communications, 56(73), 10738-10741. doi:10.1039/d0cc04426a.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-D33D-7 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-D33E-6
Genre: Journal Article

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 Creators:
Park V, Sungho1, Author
Fry, Charles G.1, Author
Bill, Eckhard2, Author           
Berry, John F.3, Author           
Affiliations:
1external, ou_persistent22              
2Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023871              
3External Organizations, ou_persistent22              

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 Abstract: The metastable purple [(Py5Me2)Ru-III(N-3)](2+)ion reacts with PPh(3)at room temperature to form the phosphinimine complex [(Py5Me2)Ru-II(N(H)PPh3)](2+)and free [H2NPPh3](+)in a combined 23% conversion. Mechanistic studies suggest that this is the first metallo-Staudinger reaction of a late transition metal that bypasses the nitrido mechanism and instead utilizes a Ru-N=N=N-PPh(3)phosphazide intermediate.

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Language(s): eng - English
 Dates: 2020
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: ISI: 000569981900026
DOI: 10.1039/d0cc04426a
 Degree: -

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Title: Chemical Communications
  Other : Chem. Commun.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 56 (73) Sequence Number: - Start / End Page: 10738 - 10741 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413