Coordination polymers of Ag(i) and Hg(i) ions with 2,2 '-azobispyridine: 
synthesis, characterization and enhancement of conductivity in the presence of 
Cu(ii) ions

Maity, Suvendu; Naskar, Kaushik; Bhowmik, Tanmay; Bera, Amalendu; Weyhermüller, Thomas; Sinha, Chittaranjan; Ghosh, Prasanta

doi:10.1039/d0dt01470b

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Coordination polymers of Ag(i) and Hg(i) ions with 2,2 '-azobispyridine: synthesis, characterization and enhancement of conductivity in the presence of Cu(ii) ions

Maity, S., Naskar, K., Bhowmik, T., Bera, A., Weyhermüller, T., Sinha, C., et al. (2020). Coordination polymers of Ag(i) and Hg(i) ions with 2,2 '-azobispyridine: synthesis, characterization and enhancement of conductivity in the presence of Cu(ii) ions. Dalton Transactions, 49(25), 8438-8442. doi:10.1039/d0dt01470b.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-D2EC-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-D2ED-1

Genre: Journal Article

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Creators:
Maity, Suvendu¹, Author
Naskar, Kaushik¹, Author
Bhowmik, Tanmay¹, Author
Bera, Amalendu¹, Author
Weyhermüller, Thomas², Author
Sinha, Chittaranjan¹, Author
Ghosh, Prasanta¹, Author

Affiliations:
1external, ou_persistent22
2Research Department DeBeer, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023871

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Abstract: The cationic coordination polymers (CPs) of the types [Hg-2(abpy)(2)](n)[PF6](2n)(1) and [Ag(abpy)](n)[PF6](n)(2) (abpy = 2,2 '-azobispyridine) were synthesized and characterized. Experimentation using the crystals confirmed that1and2are conductors of electricity. The relative conductivity of1is 62 times greater than that of2. The conductivity of1increases 70 fold when it reacts with Cu(2+)ions.

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Language(s): eng - English

Dates: Date issued: 2020

Publication Status: Issued

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Rev. Type: Peer

Identifiers: ISI: 000544124600003
DOI: 10.1039/d0dt01470b

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Title: Dalton Transactions

Abbreviation : Dalton Trans.

Source Genre: Journal

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Publ. Info: Cambridge, UK : Royal Society of Chemistry

Pages: - Volume / Issue: 49 (25) Sequence Number: - Start / End Page: 8438 - 8442 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323