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  Investigation of the rotational motion of self-assembled fatty acid films: An electron paramagnetic resonance line shape analysis

Risse, T., Hill, T., Schmidt, J., Abend, G., Hamann, H., & Freund, H.-J. (1998). Investigation of the rotational motion of self-assembled fatty acid films: An electron paramagnetic resonance line shape analysis. The Journal of Chemical Physics, 108(20), 8615-8625. doi:10.1063/1.476292.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0007-4F0B-6 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-655B-2
Genre: Journal Article

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 Creators:
Risse, Thomas1, Author           
Hill, Thomas1, Author           
Schmidt, Jörg1, Author           
Abend, Günter2, Author           
Hamann, Heiko1, Author           
Freund, Hans-Joachim1, Author           
Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              
2Fritz Haber Institute, Max Planck Society, ou_24021              

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 Abstract: We have investigated the electron paramagnetic resonance (EPR) of self-assembled stearic acid films adsorbed on an Al2O3-film. Doping the film with spin labels at different positions of the alkyl chain in order to make the films accessible for EPR spectroscopy provides an opportunity to investigate the rotational motion of the molecule along the alkyl chain. The temperature dependent EPR spectra show a strong dependence of the rotational motion of the molecules with variation of the location of the spin label along the chain. We study the rotational motion by means of the EPR line shape analysis.

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Language(s): eng - English
 Dates: 1998-02-161998-05-131998-05-22
 Publication Status: Issued
 Pages: 12
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.476292
 Degree: -

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Title: The Journal of Chemical Physics
  Other : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: 12 Volume / Issue: 108 (20) Sequence Number: - Start / End Page: 8615 - 8625 Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226