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  Cage Adaption by High-Pressure Synthesis: The Clathrate-I Borosilicide Rb8B8Si38

Hübner, J.-M., Jung, W., Schmidt, M., Bobnar, M., Koželj, P., Böhme, B., et al. (2020). Cage Adaption by High-Pressure Synthesis: The Clathrate-I Borosilicide Rb8B8Si38. Inorganic Chemistry. doi:10.1021/acs.inorgchem.0c02357.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0007-7D96-4 Version Permalink: http://hdl.handle.net/21.11116/0000-0007-B126-6
Genre: Journal Article

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 Creators:
Hübner, Julia-Maria1, Author              
Jung, Walter1, Author              
Schmidt, Marcus2, Author              
Bobnar, Matej1, Author              
Koželj, Primož1, Author              
Böhme, Bodo3, Author              
Baitinger, Michael4, Author              
Etter, Martin1, Author              
Grin, Yuri5, Author              
Schwarz, Ulrich6, Author              
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Marcus Schmidt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863415              
3Bodo Böhme, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863408              
4Michael Baitinger, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863416              
5Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              
6Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423              

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 Abstract: Rb8B8Si38 forms under high-pressure, high-temperature conditions at p = 8 GPa and T = 1273 K. The new compound (space group Pm3¯ n, a = 9.9583(1) Å) is the second example for a clathrate-I borosilicide. The phase is inert against strong acids and bases and thermally stable up to 1300 K at ambient pressure. (Rb+)8(B-)8(Si0)38 is electronically balanced, diamagnetic, and shows semiconducting behavior with moderate Seebeck coefficient below 300 K. Chemical bonding analysis by the electron localizability approach confirms the description of Rb8B8Si38 as Zintl phase. © 2020 American Chemical Society.

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Language(s): eng - English
 Dates: 2020-10-262020-10-26
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1021/acs.inorgchem.0c02357
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Title: Inorganic Chemistry
  Abbreviation : Inorg. Chem.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: - Sequence Number: - Start / End Page: - Identifier: ISSN: 0020-1669
CoNE: https://pure.mpg.de/cone/journals/resource/0020-1669