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  Electrical and thermal transport properties of natural and synthetic FeAsxS2-x (x ≤ 0.01)

Zuñiga-Puelles, E., Cardoso-Gil, R., Bobnar, M., Veremchuk, I., Heide, G., & Gumeniuk, R. (2020). Electrical and thermal transport properties of natural and synthetic FeAsxS2-x (x ≤ 0.01). Journal of Physics and Chemistry of Solids. doi:10.1016/j.jpcs.2020.109809.

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Item Permalink: http://hdl.handle.net/21.11116/0000-0007-7DE2-E Version Permalink: http://hdl.handle.net/21.11116/0000-0007-7DE4-C
Genre: Journal Article

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 Creators:
Zuñiga-Puelles, E.1, Author              
Cardoso-Gil, R.2, Author              
Bobnar, M.1, Author              
Veremchuk, I.3, Author              
Heide, G.4, Author
Gumeniuk, R.4, Author
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Raul Cardoso, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863420              
3Igor Veremchuk, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863411              
4External Organizations, ou_persistent22              

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 Abstract: The combined powder X-ray diffraction, microstructural, local and bulk chemical analyses of natural pyrite single crystals from Reiche Zeche, Johangeorgenstadt and Pretzchendorf (Erzgebirge, Saxony, Germany) showed compositions FeAs0.002(1)S1.998(9), FeAs0.004(1)S1.996(9) and FeAs0.005(1)S1.995(9), respectively. The arsenic doping leads to smaller semiconducting energy gaps (Eg ~0.1–0.2 eV) in comparison with binary FeS2 (Eg = 0.96 eV), as well as switching of conduction type mechanism from n-to the p-type. These findings are supported by the measurements of the electrical resistivity and Seebeck coefficient of the synthetic FeAsxS2-x series (maximal As-content x = 0.01 at 773 K). The investigations of sintered FeS2 + MO2 (M = Si, Ti, Zr) composites indicate that some insulating metal oxides as impurities influence less the electrical transport properties of pyrite. All performed studies unambiguously confirmed that p-type conductivity for T gt; 300 K is a hallmark of the ternary As-doped FeAsxS2-x (x ≥ 0.002) pyrites. © 2020

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Language(s): eng - English
 Dates: 2020-10-242020-10-24
 Publication Status: Published in print
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 Rev. Type: -
 Identifiers: DOI: 10.1016/j.jpcs.2020.109809
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Title: Journal of Physics and Chemistry of Solids
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: - Sequence Number: - Start / End Page: - Identifier: ISSN: 0022-3697
CoNE: https://pure.mpg.de/cone/journals/resource/110992357322388