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  Modeling the Formation, Degradation, and Spatiotemporal Distribution of 2-Nitrofluoranthene and 2-Nitropyrene in the Global Atmosphere

Wilson, J., Octaviani, M., Bandowe, B. A. M., Wietzoreck, M., Zetzsch, C., Pöschl, U., et al. (2020). Modeling the Formation, Degradation, and Spatiotemporal Distribution of 2-Nitrofluoranthene and 2-Nitropyrene in the Global Atmosphere. Environmental Science & Technology, 54(22), 14224-14234. doi:10.1021/acs.est.0c04319.

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Genre: Journal Article

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 Creators:
Wilson, Jake1, Author              
Octaviani, Mega1, Author              
Bandowe, Benjamin A. Musa1, Author              
Wietzoreck, Marco1, Author              
Zetzsch, Cornelius1, Author              
Pöschl, Ulrich1, Author              
Berkemeier, Thomas1, Author              
Lammel, Gerhard1, Author              
Affiliations:
1Multiphase Chemistry, Max Planck Institute for Chemistry, Max Planck Society, ou_1826290              

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 Abstract: Polycyclic aromatic hydrocarbons (PAHs) are common atmospheric pollutants and known to cause adverse health effects. Nitrated PAHs (NPAHs) are formed in combustion activities and by nitration of PAHs in the atmosphere and may be equally or more toxic, but their spatial and temporal distribution in the atmosphere is not well characterized. Using the global EMAC model with atmospheric chemistry and surface compartments coupled, we investigate the formation, abundance, and fate of two secondarily formed NPAHs, 2-nitrofluoranthene (2-NFLT) and 2-nitropyrene (2-NPYR). The default reactivity scenario, the model with the simplest interpretation of parameters from the literature, tends to overestimate both absolute concentrations and NPAH/PAH ratios at observational sites. Sensitivity scenarios indicate that NO2-dependent NPAH formation leads to better agreement between measured and predicted NPAH concentrations and that photodegradation is the most important loss process of 2-NFLT and 2-NPYR. The highest concentrations of 2-NFLT and 2-NPYR are found in regions with strong PAH emissions, but because of continued secondary formation from the PAH precursors, these two NPAHs are predicted to be spread across the globe.

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Language(s): eng - English
 Dates: 2020-10-28
 Publication Status: Published online
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1021/acs.est.0c04319
 Degree: -

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Title: Environmental Science & Technology
  Abbreviation : Environ. Sci. Technol.
Source Genre: Journal
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Publ. Info: Easton, PA : American Chemical Society
Pages: - Volume / Issue: 54 (22) Sequence Number: - Start / End Page: 14224 - 14234 Identifier: ISSN: 0013-936X
CoNE: https://pure.mpg.de/cone/journals/resource/954921342157