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  Bio-inspired thiolate metal complexes structural, spectroscopic and redox properties, reactivity

Gennari, M., Brazzolotto, D., Orio, M., Neese, F., van Gastel, M., DeBeer, S., et al. (2014). Bio-inspired thiolate metal complexes structural, spectroscopic and redox properties, reactivity. Talk presented at 12th European Biological Inorganic Chemistry Conference. Zurich, Switzerland. 2014-08-24 - 2014-08-28. doi:10.1007/s00775-014-1157-y.

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 Creators:
Gennari, Marcello1, Author
Brazzolotto, Deborah1, Author
Orio, Maylis2, Author
Neese, Frank3, Author              
van Gastel, Maurice3, Author              
DeBeer, Serena3, Author              
Pécaut, Jacques4, Author
Affiliations:
1Département de Chimie Moléculaire, Université J. Fourier, CNRS, Grenoble, France, ou_persistent22              
2Laboratoire de Spectrochimie Infrarouge et Raman, CNRS, Villeneuve d’Ascq, France, ou_persistent22              
3Research Department Neese, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023886              
4CEA-Grenoble, INAC , Grenoble, France, ou_persistent22              

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 Abstract: Metal sulfur bonds are largely found in metalloenzymes, and lead to specific spectroscopic properties and original reactivity in comparison with complexes containing only N-or/and O-based ligands. On the other hand, synthetic complexes with metal-thiolate bonds have revealed some interesting properties that could be involved in biological processes. However, to rationalize the reactivity of such systems, a deep investigation of their electronic properties is required. In this context, we have synthesized and characterized series of aliphatic thiolate complexes with various transition metal ions (Ni, Co, Zn, Cu, Mn, V) [1–3]. Their electronic properties have been explored via different spectroscopic techniques combined with quantum chemistry. More recently, we went a step further by looking at their reactivity, especially their ability to activate small molecules, or to form disulfide bridges and how this process can be controlled.

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Language(s): eng - English
 Dates: 2014-07-222014-08-01
 Publication Status: Published in print
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Internal
 Identifiers: DOI: 10.1007/s00775-014-1157-y
 Degree: -

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Title: 12th European Biological Inorganic Chemistry Conference
Place of Event: Zurich, Switzerland
Start-/End Date: 2014-08-24 - 2014-08-28
Invited: Yes

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Title: Journal of Biological Inorganic Chemistry
  Abbreviation : J. Biol. Inorg. Chem.
Source Genre: Journal
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Publ. Info: Berlin : Springer
Pages: - Volume / Issue: 19 (Suppl. 2) Sequence Number: - Start / End Page: S731 - S732 Identifier: ISSN: 0949-8257
CoNE: https://pure.mpg.de/cone/journals/resource/954925573943