Mastering extreme size constraints in the clathrate-I borosilicide Cs8B8Si38

Hübner, Julia-Maria; Jung, Walter; Kozelj, Primož; Bobnar, Matej; Cardoso Gil, Raul; Burkhardt, Ulrich; Böhme, Bodo; Baitinger, Michael; Schwarz, Ulrich; Grin, Yuri

doi:10.1002/zaac.202000400

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Mastering extreme size constraints in the clathrate-I borosilicide Cs₈B₈Si₃₈

Hübner, J.-M., Jung, W., Kozelj, P., Bobnar, M., Cardoso Gil, R., Burkhardt, U., et al. (2021). Mastering extreme size constraints in the clathrate-I borosilicide Cs₈B₈Si₃₈. Zeitschrift für anorganische und allgemeine Chemie, 647(2-3), 119-125. doi:10.1002/zaac.202000400.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0008-031A-8 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-35D5-C

Genre: Journal Article

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Creators:
Hübner, Julia-Maria¹, Author
Jung, Walter¹, Author
Kozelj, Primož¹, Author
Bobnar, Matej¹, Author
Cardoso Gil, Raul², Author
Burkhardt, Ulrich³, Author
Böhme, Bodo⁴, Author
Baitinger, Michael⁵, Author
Schwarz, Ulrich⁶, Author
Grin, Yuri⁷, Author

Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405
2Raul Cardoso, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863420
3Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422
4Bodo Böhme, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863408
5Michael Baitinger, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863416
6Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423
7Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413

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Free keywords: Boron, cesium, clathrate-I, high-pressure synthesis, silicon

Abstract: Cs8B8Si38 is obtained by high-pressure high-temperature synthesis at p=8 GPa and T=1273 K. The new compound (space group Pm (Formula presented.) n; a=10.0312(3) Å) is the third example for a clathrate-I borosilicide after the potassium and rubidium varieties, respectively. The phase slowly deteriorates in air and moisture but is thermally stable up to 1050 K at ambient pressure. [Cs+]8[B–]8[Si0]38 is electronically balanced, diamagnetic, and shows semiconducting behavior. © 2021 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH

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Language(s): eng - English

Dates: Published Online: 2021-01-22Date issued: 2021-01-22

Publication Status: Issued

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Identifiers: DOI: 10.1002/zaac.202000400

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Title: Zeitschrift für anorganische und allgemeine Chemie

Other : J. Inorg. Gen Chem.

Other : Journal of Inorganic and General Chemistry

Abbreviation : Z. Anorg. Allg. Chem.

Source Genre: Journal

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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH

Pages: - Volume / Issue: 647 (2-3) Sequence Number: - Start / End Page: 119 - 125 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895