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  Mastering extreme size constraints in the clathrate-I borosilicide Cs8B8Si38

Hübner, J.-M., Jung, W., Kozelj, P., Bobnar, M., Cardoso Gil, R., Burkhardt, U., et al. (2021). Mastering extreme size constraints in the clathrate-I borosilicide Cs8B8Si38. Zeitschrift für anorganische und allgemeine Chemie, 647(2-3), 119-125. doi:10.1002/zaac.202000400.

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 Creators:
Hübner, Julia-Maria1, Author              
Jung, Walter1, Author              
Kozelj, Primož1, Author              
Bobnar, Matej1, Author              
Cardoso Gil, Raul2, Author              
Burkhardt, Ulrich3, Author              
Böhme, Bodo4, Author              
Baitinger, Michael5, Author              
Schwarz, Ulrich6, Author              
Grin, Yuri7, Author              
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Raul Cardoso, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863420              
3Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
4Bodo Böhme, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863408              
5Michael Baitinger, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863416              
6Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423              
7Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              

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Free keywords: Boron, cesium, clathrate-I, high-pressure synthesis, silicon
 Abstract: Cs8B8Si38 is obtained by high-pressure high-temperature synthesis at p=8 GPa and T=1273 K. The new compound (space group Pm (Formula presented.) n; a=10.0312(3) Å) is the third example for a clathrate-I borosilicide after the potassium and rubidium varieties, respectively. The phase slowly deteriorates in air and moisture but is thermally stable up to 1050 K at ambient pressure. [Cs+]8[B–]8[Si0]38 is electronically balanced, diamagnetic, and shows semiconducting behavior. © 2021 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH

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Language(s): eng - English
 Dates: 2021-01-222021-01-22
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/zaac.202000400
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : J. Inorg. Gen Chem.
  Other : Journal of Inorganic and General Chemistry
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 647 (2-3) Sequence Number: - Start / End Page: 119 - 125 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895