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  Emerging concepts in photocatalytic organic synthesis

Reischauer, S., & Pieber, B. (2021). Emerging concepts in photocatalytic organic synthesis. iScience, 24(3): 102209. doi:10.1016/j.isci.2021.102209.

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Reischauer, Susanne1, Author              
Pieber, Bartholomäus1, Author              
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1Bartholomäus Pieber, Biomolekulare Systeme, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_2522692              

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Free keywords: photocatalysis; organic synthesis; medicinal chemistry; chromoselectivity; flow chemistry
 Abstract: Visible light photocatalysis has become a powerful tool in organic synthesis that uses photons as traceless, sustainable reagents. Most of the activities in the field focus on the development of new reactions via common photoredox cycles, but recently a number of exciting new concepts and strategies entered less charted territories. We survey approaches that enable the use of longer wavelengths and show that the wavelength and intensity of photons are import parameters that enable tuning of the reactivity of a photocatalysts to control or change the selectivity of chemical reactions. In addition, we discuss recent efforts to substitute strong reductants, such as elemental lithium and sodium, by light, and technological advances in the field.

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Language(s): eng - English
 Dates: 2021-02-182021
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1016/j.isci.2021.102209
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Title: iScience
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: - Volume / Issue: 24 (3) Sequence Number: 102209 Start / End Page: - Identifier: ISSN: 2589-0042