Insights into the Chemistry of Transient P‐Chlorophosphanyl Complexes

Özbolat‐Schön, Aysel; Bode, Maren; Schnakenburg, Gregor; Anoop, Anakuthil; van Gastel, Maurice; Neese, Frank; Streubel, Rainer

doi:10.1002/anie.201002885

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Insights into the Chemistry of Transient P‐Chlorophosphanyl Complexes

Özbolat‐Schön, A., Bode, M., Schnakenburg, G., Anoop, A., van Gastel, M., Neese, F., et al. (2010). Insights into the Chemistry of Transient P‐Chlorophosphanyl Complexes. Angewandte Chemie International Edition, 49(38), 6894-6898. doi:10.1002/anie.201002885.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0008-0FAB-8 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-0FAC-7

Genre: Journal Article

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Creators:
Özbolat‐Schön, Aysel¹, Author
Bode, Maren¹, Author
Schnakenburg, Gregor¹, Author
Anoop, Anakuthil², Author
van Gastel, Maurice², Author
Neese, Frank², Author
Streubel, Rainer¹, Author

Affiliations:
1Institut für Anorganische Chemie der Rheinischen Friedrich‐Wilhelms‐Universität Bonn, Gerhard‐Domagk‐Strasse 1, 53121 Bonn (Germany), ou_persistent22
2Lehrstuhl für Theoretische Chemie, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Wegelerstrasse 12, D-53115 Bonn, Germany, ou_persistent22

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Free keywords: EPR spectroscopy; phosphanyl complexes; phosphaquinomethane; phosphinidenoid complexes; tritylium salts

Abstract: C-P or C=P? One‐electron oxidation of Li/Cl phosphinidenoid complexes led to the discovery of transient P‐chlorophosphanyl complexes 1. Subsequent cross‐coupling and rearrangement or elimination reactions yielded 2 and 3; the latter is the first structurally characterized phosphaquinomethane complex. ESR spectroscopy and DFT calculations support the existence of short‐lived P‐centered radicals.

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Language(s): eng - English

Dates: Submitted: 2010-05-12Published Online: 2010-08-16Date issued: 2010-09-10

Publication Status: Issued

Pages: 5

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Table of Contents: -

Rev. Type: Peer

Identifiers: DOI: 10.1002/anie.201002885

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Title: Angewandte Chemie International Edition

Abbreviation : Angew. Chem., Int. Ed.

Source Genre: Journal

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Publ. Info: Weinheim : Wiley-VCH

Pages: - Volume / Issue: 49 (38) Sequence Number: - Start / End Page: 6894 - 6898 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851