English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  X‐Ray Structures of Copper(II) and Nickel(II) Radical Salen Complexes: The Preference of Galactose Oxidase for Copper(II)

Orio, M., Jarjayes, O., Kanso, H., Philouze, C., Neese, F., & Thomas, F. (2010). X‐Ray Structures of Copper(II) and Nickel(II) Radical Salen Complexes: The Preference of Galactose Oxidase for Copper(II). Angewandte Chemie International Edition, 49(29), 4989-4992. doi:10.1002/anie.201001040.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-0008-0FA5-E Version Permalink: https://hdl.handle.net/21.11116/0000-0008-0FA6-D
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Orio, Maylis1, Author
Jarjayes, Olivier2, Author
Kanso, Hussein2, Author
Philouze, Christian2, Author
Neese, Frank1, Author           
Thomas, Fabrice2, Author
Affiliations:
1Lehrstuhl für Theoretische Chemie, Institut für Physikalische und Theoretische Chemie, Universität Bonn, Wegelerstrasse 12, D-53115 Bonn, Germany, ou_persistent22              
2Département de Chimie Moléculaire, Chimie Inorganique, Redox Biomimétique (CIRE), UMR CNRS 5250, Université Joseph Fourier, B.P. 53, 38041 Grenoble cedex 9 (France), ou_persistent22              

Content

show
hide
Free keywords: copper; enzyme models; nickel; radicals;Schiff base ligands
 Abstract: Copper or nickel? The depicted CuII salen complex, an active‐site model of galactose oxidase (GO), is a localized radical in the solid state with a quinoid distribution of bond lengths in one ring. While the ligand‐radical structure is not metal‐dependent, the composition of the radical SOMO is. This feature may explain the much lower reactivity of the Ni complex and nature's preference for a CuII center in GO.

Details

show
hide
Language(s): eng - English
 Dates: 2010-02-192010-06-292010-07-05
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201001040
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 49 (29) Sequence Number: - Start / End Page: 4989 - 4992 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851