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  The Reduced Nitridogermanates(III) Ca6[Ge2N6] and Sr6[Ge2N6] with Ge-Ge Bonds

Link, L., Pathak, M., Jach, F., Koželj, P., Ormeci, A., Höhn, P., et al. (2021). The Reduced Nitridogermanates(III) Ca6[Ge2N6] and Sr6[Ge2N6] with Ge-Ge Bonds. Angewandte Chemie International Edition, 60(14), 7691-7696. doi:10.1002/anie.202017270.

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 Creators:
Link, L.1, Author
Pathak, M.2, Author              
Jach, F.1, Author
Koželj, P.2, Author              
Ormeci, A.2, Author              
Höhn, P.3, Author              
Niewa, R.1, Author
Affiliations:
1External Organizations, ou_persistent22              
2Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
3Peter Höhn, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863419              

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 Abstract: The first nitridogermanates(III) Ca-6[Ge2N6] and Sr-6[Ge2N6] were synthesized from sodium flux and structurally characterized by powder and single crystal X-ray diffraction, respectively. They crystallize isostructurally to each other and homeotypic to Ca-6[Cr2N6]H in space group R3? . They feature unprecedented, mutually isolated, ethane-like [(Ge2N6)-N-III](12-) anions in a staggered conformation. The compounds are semiconductors according to resistivity measurements and electronic structure calculations, yielding band gaps of 1.1 eV for Ca-6[Ge2N6] and 0.2 eV for Sr-6[Ge2N6].

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Language(s): eng - English
 Dates: 2021-02-012021-02-01
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000618967700001
DOI: 10.1002/anie.202017270
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 60 (14) Sequence Number: - Start / End Page: 7691 - 7696 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851