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  EPR Spectroscopy of a Family of CrIII7MII (M = Cd, Zn, Mn, Ni) “Wheels”: Studies of Isostructural Compounds with Different Spin Ground States

Piligkos, S., Weihe, H., Bill, E., Neese, F., El Mkami, H., Smith, G. M., et al. (2009). EPR Spectroscopy of a Family of CrIII7MII (M = Cd, Zn, Mn, Ni) “Wheels”: Studies of Isostructural Compounds with Different Spin Ground States. Chemistry – A European Journal, 15(13), 3152-3167. doi:10.1002/chem.200801895.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0008-333B-D Version Permalink: https://hdl.handle.net/21.11116/0000-0008-333C-C
Genre: Journal Article

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 Creators:
Piligkos, Stergios1, 2, 3, Author           
Weihe, Høgni1, Author
Bill, Eckhard2, Author           
Neese, Frank2, Author           
El Mkami, Hassane4, Author
Smith, Graham M.4, Author
Collison, David3, Author
Rajaraman, Gopalan3, Author
Timco, Grigore A.3, Author
Winpenny, Richard E. P.3, Author
McInnes, Eric J. L.3, Author
Affiliations:
1Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen (Denmark), ou_persistent22              
2Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society, ou_3023881              
3School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester (UK), ou_persistent22              
4School of Physics and Astronomy, University of St Andrews, North Haugh, KY16 SS, St. Andrews (UK), ou_persistent22              

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Free keywords: davidson algorithm; effective subspaces; EPR spectroscopy; heterometallic wheels; S-mixing
 Abstract: Spinning wheels: The presented highly resolved multifrequency continuous wave EPR spectra (e.g., see figure) of the heterooctametalic “wheels” Cr7M provide rare examples of high nuclearity polymetallic systems where detailed information on the spin‐Hamiltonian parameters of the ground and excited spin states is observed.

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Language(s): eng - English
 Dates: 2009-03-062009-03-16
 Publication Status: Issued
 Pages: 16
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/chem.200801895
 Degree: -

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Title: Chemistry – A European Journal
  Other : Chem. – Eur. J.
  Other : Chem. Eur. J.
Source Genre: Journal
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Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 15 (13) Sequence Number: - Start / End Page: 3152 - 3167 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058