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  The Geometric and Electronic Structure of [(cyclam‐acetato)Fe(N)]+: A Genuine Iron(V) Species with a Ground‐State Spin S=1/2

Aliaga-Alcade, N., DeBeer George, S., Mienert, B., Bill, E., Wieghardt, K., & Neese, F. (2005). The Geometric and Electronic Structure of [(cyclam‐acetato)Fe(N)]+: A Genuine Iron(V) Species with a Ground‐State Spin S=1/2. Angewandte Chemie International Edition, 44(19), 2908-2912. doi:10.1002/anie.200462368.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0008-36B9-B Version Permalink: https://hdl.handle.net/21.11116/0000-0008-36BA-A
Genre: Journal Article

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 Creators:
Aliaga-Alcade, Núria1, Author           
DeBeer George, Serena2, Author
Mienert, Bernd1, Author           
Bill, Eckhard1, Author           
Wieghardt, Karl1, Author           
Neese, Frank1, Author           
Affiliations:
1Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society, ou_3023881              
2Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94309, USA, ou_persistent22              

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Free keywords: electronic structure; EXAFS spectroscopy; iron; Mössbauer spectroscopy; nitrido ligands
 Abstract: Low‐spin, high‐valent iron centers: A high‐valent iron–nitrido species containing a FeV center is accessible by the photolysis of [(cyclam‐ac)FeIIIN3]+. The identity of the resulting [(cyclam‐ac)FeV(N)]+ species was verified by spectroscopic methods, magnetic susceptibility data, and DFT calculations (see picture). Unexpectedly, the analysis provides strong evidence for a low‐spin d3 (S=1/2) ground‐state electron configuration at the FeV center.

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Language(s): eng - English
 Dates: 2004-10-202005-05-032005-05-06
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200462368
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 44 (19) Sequence Number: - Start / End Page: 2908 - 2912 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851