English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
  An Octahedral Coordination Complex of Iron(VI)

Berry, J. F., Bill, E., Bothe, E., DeBeer George, S., Mienert, B., Neese, F., et al. (2006). An Octahedral Coordination Complex of Iron(VI). Science, 312(5782), 1937-1941. doi:10.1126/science.1128506.

Item is

Basic

show hide
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Berry, John F.1, Author              
Bill, Eckhard1, Author              
Bothe, Eberhard1, Author              
DeBeer George, Serena2, Author
Mienert, Bernd1, Author              
Neese, Frank1, Author              
Wieghardt, Karl1, Author              
Affiliations:
1Research Department Wieghardt, Max Planck Institute for Bioinorganic Chemistry, Max Planck Society, ou_3023881              
2Stanford Synchrotron Radiation Laboratory, Stanford University, Stanford, CA 94309, USA, ou_persistent22              

Content

show
hide
Free keywords: -
 Abstract: The hexavalent state, considered to be the highest oxidation level accessible for iron, has previously been found only in the tetrahedral ferrate dianion, FeO42–. We report the photochemical synthesis of another Fe(VI) compound, an octahedrally coordinated dication bearing a terminal nitrido ligand. Mössbauer and x-ray absorption spectra, supported by density functional theory, are consistent with the octahedral structure having an Fe≡N triple bond of 1.57 angstroms and a singlet d2xy ground electronic configuration. The compound is stable at 77 kelvin and yields a high-spin Fe(III) species upon warming.

Details

show
hide
Language(s): eng - English
 Dates: 2006-06-30
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1126/science.1128506
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Science
  Abbreviation : Science
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Washington, D.C. : American Association for the Advancement of Science
Pages: - Volume / Issue: 312 (5782) Sequence Number: - Start / End Page: 1937 - 1941 Identifier: ISSN: 0036-8075
CoNE: https://pure.mpg.de/cone/journals/resource/991042748276600_1