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  Ruthenium‐Catalyzed Dehydrogenation Through an Intermolecular Hydrogen Atom Transfer Mechanism

Huang, L., Bismuto, A., Rath, S. A., Trapp, N., & Morandi, B. (2021). Ruthenium‐Catalyzed Dehydrogenation Through an Intermolecular Hydrogen Atom Transfer Mechanism. Angewandte Chemie International Edition, 60(13), 7290-7296. doi:10.1002/anie.202015837.

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Genre: Journal Article

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 Creators:
Huang, Lin1, 2, Author              
Bismuto, Alessandro2, Author
Rath, Simon A.2, Author
Trapp, Nils2, Author
Morandi, Bill1, 2, Author              
Affiliations:
1Research Group Morandi, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040309              
2Laboratorium für Organische Chemie ETH Zürich, Vladimir-Prelog-Weg 3, HCI, 8093 Zürich, Switzerland, ou_persistent22              

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Free keywords: alkenes; aryl radicals; dehydrogenation; hydrogenation atom transfer; redox-actine ligands
 Abstract: The direct dehydrogenation of alkanes is among the most efficient ways to access valuable alkene products. Although several catalysts have been designed to promote this transformation, they have unfortunately found limited applications in fine chemical synthesis. Here, we report a conceptually novel strategy for the catalytic, intermolecular dehydrogenation of alkanes using a ruthenium catalyst. The combination of a redox‐active ligand and a sterically hindered aryl radical intermediate has unleashed this novel strategy. Importantly, mechanistic investigations have been performed to provide a conceptual framework for the further development of this new catalytic dehydrogenation system.

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Language(s): eng - English
 Dates: 2020-11-272021-01-052021-03-22
 Publication Status: Published in print
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.202015837
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 60 (13) Sequence Number: - Start / End Page: 7290 - 7296 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851