English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Site-Selective Late-Stage C–H Functionalization via Thianthrenium Salts

Berger, F., & Ritter, T. (2022). Site-Selective Late-Stage C–H Functionalization via Thianthrenium Salts. Synlett, 33(4), 339-345. doi:10.1055/s-0040-1706034.

Item is

Basic

show hide
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Berger, Florian1, Author              
Ritter, Tobias1, Author              
Affiliations:
1Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040308              

Content

show
hide
Free keywords: C-H functionalization; selectivity; sulfonium salts; cross-coupling; photoredox catalysis
 Abstract: The high abundance of C–H bonds in organic molecules makes C–H functionalization a powerful approach to quickly increase the complexity of an organic molecule. However, the high abundance of C–H bonds also provides a challenge to C–H functionalization reactions: selectivity. While most C–H functionalization reactions produce mixtures of different products for most substrates, we have developed a highly selective method for aromatic C–H functionalization via sulfonium salts. The reaction does not require a certain directing group to be selective. The introduced functional group is a sulfonium group, which participates in various follow-up reactions such as palladium-catalyzed cross-coupling reactions and photoredox catalysis. Here we discuss our pathway to develop the reaction as well as its scope and utility.

Details

show
hide
Language(s): eng - English
 Dates: 2021-03-042021-04-132022-03-01
 Publication Status: Published in print
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/s-0040-1706034
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 33 (4) Sequence Number: - Start / End Page: 339 - 345 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856