English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  Light‐Driven gem‐Hydrogenation: An Orthogonal Entry into “Second Generation” Ruthenium Carbene Catalysts for Olefin Metathesis

Zachmann, R. J., & Fürstner, A. (2021). Light‐Driven gem‐Hydrogenation: An Orthogonal Entry into “Second Generation” Ruthenium Carbene Catalysts for Olefin Metathesis. Chemistry – A European Journal, 27(28), 7663-7666. doi:10.1002/chem.202101176.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-0008-B307-6 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-B308-5
Genre: Journal Article

Files

show Files
hide Files
:
chem202101176-s1-si_light_driven_synthesis_of_grubbs-hoveyda_complexes_v3.pdf (Supplementary material), 7MB
View   Save
File Permalink:
https://hdl.handle.net/21.11116/0000-0008-B309-4
Name:
chem202101176-s1-si_light_driven_synthesis_of_grubbs-hoveyda_complexes_v3.pdf
Description:
Supporting Information
OA-Status:
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
View
Copyright Date:
-
Copyright Info:
-
License:
-

Locators

show

Creators

show
hide
 Creators:
Zachmann, Raphael J.1, Author           
Fürstner, Alois1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

Content

show
hide
Free keywords: gem-hydrogenation; Grubbs catalysts; metal carbenes; metathesis; ruthenium
 Abstract: The newly discovered light‐driven gem‐hydrogenation of alkynes opens an unconventional yet efficient entry into five‐coordinate Grubbs‐type ruthenium carbene complexes with cis‐disposed chloride ligands. Representatives of this class featuring a chelate substructure formed by an iodo‐substituted benzylidene unit react with (substituted) 2‐isopropoxystyrene to give prototypical “second generation” Grubbs‐Hoveyda complexes for olefin metathesis. The new approach to this venerable catalyst family is safe and versatile for it uses a triple bond rather than phenyldiazomethane as the ultimate carbene source and does not require any sacrificial phosphines.

Details

show
hide
Language(s): eng - English
 Dates: 2021-04-012021-04-192021-04-192021-05-17
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/chem.202101176
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Chemistry – A European Journal
  Other : Chem. – Eur. J.
  Other : Chem. Eur. J.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 27 (28) Sequence Number: - Start / End Page: 7663 - 7666 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058