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Abstract:
Recent experimental realizations of strong coupling between optical cavity modes and molecular matter placed inside the cavity have opened exciting new routes for controlling chemical processes. Simulating the cavity-modified dynamics of complex chemical systems calls for the development of accurate, flexible, and cost-effective approximate numerical methods that scale favorably with system size and complexity. In this Letter, we test the ability of quasiclassical mapping Hamiltonian methods to serve this purpose. We simulated the spontaneous emission dynamics of an atom confined to a microcavity via five different variations of the linearized semiclassical (LSC) method. Our main finding is that recently proposed LSC-based methods which use a modified form of the identity operator are reasonably accurate and perform significantly better than the Ehrenfest and standard LSC methods, without significantly increasing computational costs. These methods are therefore highly promising as a general purpose tool for simulating cavity-modified dynamics of complex chemical systems.
