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Schlagwörter:
Iron chalcogenide, Magnetism, Neutron diffraction, Phase diagram, Spin structure, Iron compounds, Magnetic structure, Neutron diffraction, Phase diagrams, Selenium compounds, Strontium compounds, Temperature, Fe$+3+$, Highest temperature, Iron chalcogenides, Lock-in, Low-temperature structure, Magnetic phase diagrams, Magnetic transitions, Powder neutron diffraction, Propagation vector, Spin structures, Magnetism
Zusammenfassung:
We here report on the complex magnetic structures within the Sr2Fe3Ch2O3 (Ch = S and Se) system that we studied by means of powder neutron diffraction. Successive magnetic transitions occur in the magnetic phase diagram of both compounds with an incommensurate character of the magnetic structure at higher temperatures and a lock-in to commensurate low temperature structures. The commensurate propagation vector for the Ch = S compound is different from the Se containing compound which could be indicative for changes in the size of competing exchange interactions implied by structural changes within the two materials. © 2021 Elsevier B.V.
