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  Oxidative photopolymerization of 3,4-ethylenedioxythiophene (EDOT) via graphitic carbon nitride : a modular toolbox for attaining PEDOT

Esen, C., Antonietti, M., & Kumru, B. (2021). Oxidative photopolymerization of 3,4-ethylenedioxythiophene (EDOT) via graphitic carbon nitride: a modular toolbox for attaining PEDOT. ChemPhotoChem, (9), 857-862. doi:10.1002/cptc.202100046.

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 Creators:
Esen, Cansu1, Author              
Antonietti, Markus2, Author              
Kumru, Baris1, Author              
Affiliations:
1Baris Kumru, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_3202957              
2Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              

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Free keywords: polymerization, Photocatalysis, Semiconductors, colloids, conducting materials
 Abstract: Conductive polymers found key applications ranging from optoelectronics and OLEDs to conductive composite materials. The synthesis of conductive polymers from monomers such as thiophene derivatives, pyrroles and aniline mainly relies on oxidative polymerization, and the processing of so-formed (insoluble) polymers is a major issue that needs to be addressed. In the present work, oxidative photopolymerization of 3,4-ethylenedioxythiophene (EDOT) by visible light employing the metal-free semiconductor graphitic carbon nitride (g-CN) is presented. Two main reaction pathways based on g-CN content will be described, and the formation of processable oligo-EDOT will be demonstrated.

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Language(s): eng - English
 Dates: 2021-05-032021
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/cptc.202100046
BibTex Citekey: https://doi.org/10.1002/cptc.202100046
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Title: ChemPhotoChem
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: 5 Volume / Issue: (9) Sequence Number: - Start / End Page: 857 - 862 Identifier: ISSN: 2367-0932