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  Circular dichroism as a detection method in the screening of enantioselective catalysts

Reetz, M. T., Kühling, K. M., Hinrichs, H., & Deege, A. (2000). Circular dichroism as a detection method in the screening of enantioselective catalysts. Chirality, 12(5-6), 479-482. doi:10.1002/(sici)1520-636x(2000)12:5/6<479:aid-chir32>3.0.co;2-#.

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 Creators:
Reetz, Manfred T.1, Author           
Kühling, Klaus M.1, Author
Hinrichs, Heike2, Author           
Deege, Alfred2, Author           
Affiliations:
1Research Department Reetz, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445588              
2Research Department Maier, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445586              

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 Abstract: The combination of liquid chromatography (HPLC), UV/Vis-spectroscopy and circular dichroism (CD) can be used to construct a high-throughput screening system to determine the enantioselectivity of enzyme- or metal-catalyzed reduction of acetophenone with formation of (S)- and (R)-1-phenylethanol. Prerequisite for the viability of this system is the experimental finding that the anisotropy factor g is linearly related to the enantiomeric excess (ee) and that it is independent of concentration, thereby excluding possible aggregation effects.

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Language(s): eng - English
 Dates: 2000-06-01
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Degree: -

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Title: Chirality
  Abbreviation : Chirality
Source Genre: Journal
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Publ. Info: New York : J. Wiley
Pages: - Volume / Issue: 12 (5-6) Sequence Number: - Start / End Page: 479 - 482 Identifier: ISSN: 0899-0042
CoNE: https://pure.mpg.de/cone/journals/resource/954925561581