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  Preparative LC separation and isolation of enantiomerically pure olefins

Köhler, J., Deege, A., & Schomburg, G. (1984). Preparative LC separation and isolation of enantiomerically pure olefins. Chromatographia, 18, 119-124. doi:10.1007/BF02258766.

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 Creators:
Köhler, J.1, Author
Deege, A.1, Author              
Schomburg, G.1, Author              
Affiliations:
1Service Department Schomburg (GC), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445628              

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Free keywords: Enantiomeric olefins; Platinum complexes; Ligand exchange; Preparative gas chromatography; Preparative column-liquid chromatography; Column switching
 Abstract: Diastereomer formation by the reaction of chiral olefins with optically active platinum complexes followed by LC separation of the diastereomers, and on-line or off-line release of the olefins from the complexes by ligand exchange yield optically pure enantiomers. The 100% dextrostetatory enantiomer of exo-2-vinylbicyclo[2.2.1]heptane (vinylnorbornane) could be isolated by an off-line method and was used for polarimetric measurements before and after preparative scale gas chromatographic clean-up. The initial valuable platinum complex could be easily recovered without loss.

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Language(s): eng - English
 Dates: 1984-03-01
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1007/BF02258766
 Degree: -

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Title: Chromatographia
  Other : Chromatographia
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Braunschweig, Germany [etc.] : Pergamon
Pages: - Volume / Issue: 18 Sequence Number: - Start / End Page: 119 - 124 Identifier: ISSN: 0009-5893
CoNE: https://pure.mpg.de/cone/journals/resource/954925390267