The size dependence of the electronic structure of Pd clusters supported on Al2O
3Re(0001)

Cai, Y. Q.; Bradshaw, Alexander M.; Guo, Q.; Goodman, D.W.

doi:10.1016/S0039-6028(98)00041-7

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The size dependence of the electronic structure of Pd clusters supported on Al₂O₃Re(0001)

Cai, Y. Q., Bradshaw, A. M., Guo, Q., & Goodman, D. (1998). The size dependence of the electronic structure of Pd clusters supported on Al₂O₃Re(0001). Surface Science, 399(2-3), L357-L363. doi:10.1016/S0039-6028(98)00041-7.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0008-A19A-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-A19B-3

Genre: Journal Article

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Creators:
Cai, Y. Q.¹, Author
Bradshaw, Alexander M.², Author
Guo, Q.³, Author
Goodman, D.W.³, Author

Affiliations:
1Theory, Fritz Haber Institute, Max Planck Society, ou_634547
2Fritz Haber Institute, Max Planck Society, ou_24021
3Department of Chemistry, Texas A and M University, USA, ou_persistent22

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Abstract: The size dependence of the electronic structure of Pd clusters deposited on an ordered Al₂O₃ film on Re(0001) has been studied using angle-resolved photoemission in conjunction with synchrotron radiation. The appearance of dispersion effects along directions both parallel and perpendicular to the substrate surface with increasing cluster size is observed, which is attributed to the formation of crystallites with a preferred orientation and signifies the non-metal to metal transition of the Pd clusters. The transition appears to take place at an estimated average cluster size of approximately 25 Å.

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Language(s): eng - English

Dates: Submitted: 1997-06-23Accepted: 1997-12-09Date issued: 1998-03-10

Publication Status: Issued

Pages: 7

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Rev. Type: Peer

Identifiers: DOI: 10.1016/S0039-6028(98)00041-7

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Title: Surface Science

Abbreviation : Surf. Sci.

Source Genre: Journal

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Publ. Info: Amsterdam : Elsevier

Pages: 7 Volume / Issue: 399 (2-3) Sequence Number: - Start / End Page: L357 - L363 Identifier: ISSN: 0039-6028
CoNE: https://pure.mpg.de/cone/journals/resource/0039-6028