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  Iron-mediated C–H coupling of arenes and unactivated terminal alkenes directed by sulfur

Cavanagh, C. W., Aukland, M. H., Hennessy, A., & Procter, D. J. (2015). Iron-mediated C–H coupling of arenes and unactivated terminal alkenes directed by sulfur. Chemical Communications, 51(45), 9272-9275. doi:10.1039/C5CC02676H.

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Genre: Journal Article

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 Creators:
Cavanagh, Craig W.1, Author
Aukland, Miles H.1, Author              
Hennessy, Alan2, Author
Procter, David J.1, Author
Affiliations:
1Department of Chemistry, University of Manchester, Manchester, UK, ou_persistent22              
2Syngenta, Jealott's Hill International Research Centre, Bracknell, Berkshire, UK, ou_persistent22              

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 Abstract: A sulfur-directed Fe(III)-mediated ortho C–H coupling of arenes with unactivated terminal alkenes gives products of regioselective alkene chloroarylation. The novel mechanism involves redox-activation of the arene partner and alkene addition to the resultant aryl radical cation.

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Language(s): eng - English
 Dates: 2015-03-312015-04-302015-06-07
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/C5CC02676H
 Degree: -

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Title: Chemical Communications
  Abbreviation : Chem. Commun.
Source Genre: Journal
 Creator(s):
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 51 (45) Sequence Number: - Start / End Page: 9272 - 9275 Identifier: ISSN: 1359-7345
CoNE: https://pure.mpg.de/cone/journals/resource/954928495413