ausblenden:
Schlagwörter:
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Zusammenfassung:
From an electrochemical investigation by means of an electrochemical quartz microbalance, a rotating disc electrode, and a ring/disc electrode, two mechanisms for the reduction of S2O82- became apparent. Besides the well-known outer-sphere cathodic reduction, a catalytic mechanism of S2O82- reduction operates in a potential range between the surface oxide region (≈-0.5 V/SCE) and -1.0 V/SCE. It involves the chemical
oxidation of the copper surface to a soluble Cu(I) species. The catalytic mechanism is concluded to result from the specific interaction between S2O82- and the Cu surface modified by the presence of subsurface
oxygen.
