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  Extreme Biomimetics: Designing of the First Nanostructured 3D Spongin-Atacamite Composite and its Application

Tsurkan, D., Simon, P., Schimpf, C., Motylenko, M., Rafaja, D., Roth, F., et al. (2021). Extreme Biomimetics: Designing of the First Nanostructured 3D Spongin-Atacamite Composite and its Application. Advanced Materials, 33(30): 2101682, pp. 1-14. doi:10.1002/adma.202101682.

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 Creators:
Tsurkan, Dmitry1, Author
Simon, Paul2, Author           
Schimpf, Christian1, Author
Motylenko, Mykhaylo1, Author
Rafaja, David1, Author
Roth, Friedrich1, Author
Inosov, Dmytro S.1, Author
Makarova, Anna A.1, Author
Stepniak, Izabela1, Author
Petrenko, Iaroslav1, Author
Springer, Armin1, Author
Langer, Enrico1, Author
Kulbakov, Anton A.1, Author
Avdeev, Maxim1, Author
Stefankiewicz, Artur R.1, Author
Heimler, Korbinian1, Author
Kononchuk, Olga1, Author
Hippmann, Sebastian1, Author
Kaiser, Doreen1, Author
Viehweger, Christine1, Author
Rogoll, Anika1, AuthorVoronkina, Alona1, AuthorKovalchuk, Valentin1, AuthorBazhenov, Vasilii V.1, AuthorGalli, Roberta1, AuthorRahimi-Nasrabadi, Mehdi1, AuthorMolodtsov, Serguei L.1, AuthorJoseph, Yvonne1, AuthorVogt, Carla1, AuthorVyalikh, Denis V.1, AuthorBertau, Martin1, AuthorEhrlich, Hermann1, Author more..
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1External Organizations, ou_persistent22              
2Paul Simon, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863418              

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 Abstract: The design of new composite materials using extreme biomimetics is of crucial importance for bioinspired materials science. Further progress in research and application of these new materials is impossible without understanding the mechanisms of formation, as well as structural features at the molecular and nano-level. It presents a challenge to obtain a holistic understanding of the mechanisms underlying the interaction of organic and inorganic phases under conditions of harsh chemical reactions for biopolymers. Yet, an understanding of these mechanisms can lead to the development of unusual-but functional-hybrid materials. In this work, a key way of designing centimeter-scale macroporous 3D composites, using renewable marine biopolymer spongin and a model industrial solution that simulates the highly toxic copper-containing waste generated in the production of printed circuit boards worldwide, is proposed. A new spongin-atacamite composite material is developed and its structure is confirmed using neutron diffraction, X-ray diffraction, high-resolution transmission electron microscopy/selected-area electron diffraction, X-ray photoelectron spectroscopy, near-edge X-ray absorption fine structure spectroscopy, and electron paramagnetic resonance spectroscopy. The formation mechanism for this material is also proposed. This study provides experimental evidence suggesting multifunctional applicability of the designed composite in the development of 3D constructed sensors, catalysts, and antibacterial filter systems.

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Language(s): eng - English
 Dates: 2021-06-032021-06-03
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000657522600001
DOI: 10.1002/adma.202101682
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Title: Advanced Materials
  Other : Adv. Mater.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 33 (30) Sequence Number: 2101682 Start / End Page: 1 - 14 Identifier: ISSN: 0935-9648
CoNE: https://pure.mpg.de/cone/journals/resource/954925570855