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Abstract:
Electron transfer over the reaction distance corresponding to three saturated bonds occurs within 70 fs from the excited singlet state of anchored perylene chromophores to empty electronic levels in a sponge-type anatase TiO2 electrode. Injected electrons can be consumed in three different types of recombination processes at the interface with the electrolytic contact. Electron transport through the electrode follows a potential gradient that is set-up in the dark, corresponding to the difference between the Fermi levels of the two contact materials. It is dominated by multiple trapping and trap filling processes.
