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  Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF3+, CF3, and CF3 Reactivity

Jia, H., Häring, A. P., Berger, F., Zhang, L., & Ritter, T. (2021). Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF3+, CF3, and CF3 Reactivity. Journal of the American Chemical Society, 143(20), 7623-7628. doi:10.1021/jacs.1c02606.

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Genre: Journal Article

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 Creators:
Jia, Hao1, Author              
Häring, Andreas P.1, Author              
Berger, Florian1, Author              
Zhang, Li1, Author              
Ritter, Tobias1, Author              
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1Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040308              

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 Abstract: Here we report the synthesis and application of trifluoromethyl thianthrenium triflate (TT-CF3+OTf) as a novel trifluoromethylating reagent, which is conveniently accessible in a single step from thianthrene and triflic anhydride. We demonstrate the use of TT-CF3+OTf in electrophilic, radical, and nucleophilic trifluoromethylation reactions.

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Language(s): eng - English
 Dates: 2021-03-092021-05-142021-05-26
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jacs.1c02606
 Degree: -

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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 143 (20) Sequence Number: - Start / End Page: 7623 - 7628 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870