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  Behaviour of the V2+ Ground State in Tetrahedrally Coordinated II–VI Semiconductors

Biernacki, S. W., Kreissl, J., & Schulz, H.-J. (1997). Behaviour of the V2+ Ground State in Tetrahedrally Coordinated II–VI Semiconductors. Zeitschrift für Physikalische Chemie, 201(1-2), 31-43. doi:10.1524/zpch.1997.201.Part_1_2.031.

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10.1524_zpch.1997.201.part_1_2.031.pdf (Publisher version), 3MB
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10.1524_zpch.1997.201.part_1_2.031.pdf
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1997
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De Gruyter
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 Creators:
Biernacki, S. W.1, Author
Kreissl, J.2, Author
Schulz, Hans-Joachim3, Author           
Affiliations:
1Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, PL-02668 Warsaw, Poland, ou_persistent22              
2Arbeitsgruppe EPR am Institut für Festkörperphysik, Technische Universität Berlin, Rudower Chaussee 5, D-12484 Berlin, Germany, ou_persistent22              
3Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

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 Abstract: The ground state of the lattice-neutral charge state of vanadium in tetrahedrally coordinated II—VI materials is a 4T1 term and is hence subject to a Jahn-Teller (JT) effect. In this paper photo-luminescence and EPR investigations on V2+ (3d3) in ZnS, ZnSe, ZnTe, and CdTe are combined with Tanabe-Sugano calculations including JT interaction. For ZnS the no-phonon structure is explained by a tunnelling splitting.

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Language(s): eng - English
 Dates: 1996-08-251996-09-231997-05-30
 Publication Status: Issued
 Pages: 13
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Degree: -

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Title: Zeitschrift für Physikalische Chemie
  Other : Zeitschrift für Physikalische Chemie: International journal of research in physical chemistry and chemical physics
  Abbreviation : Zeitschr. Phys. Chem.
Source Genre: Journal
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Publ. Info: Oldenbourg : Walter de Gruyter GmbH
Pages: 13 Volume / Issue: 201 (1-2) Sequence Number: - Start / End Page: 31 - 43 Identifier: ISSN: 0942-9352
CoNE: https://pure.mpg.de/cone/journals/resource/09429352