English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse
  1. Start / 
  2. View item

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  The selective oxidation of methanol: A comparison of the mode of action of metal and oxide catalysts

Herein, D., Werner, H., Schedel-Niedrig, T., Neisius, T., Nagy, A. J., Berndt, S., et al. (1997). The selective oxidation of methanol: A comparison of the mode of action of metal and oxide catalysts. In R. K. Grasselli, S. T. Oyama, A. M. Gaffney, & J. E. Lyons (Eds.), Proceedings of the 3rd World Congress on Oxidation Catalysis (pp. 103-122). Amsterdam: Elsevier.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-0008-E2A1-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-E2A2-1
Genre: Conference Paper

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Herein, Daniel1, Author           
Werner, Harald1, Author           
Schedel-Niedrig, Thomas1, Author           
Neisius, Thomas1, Author           
Nagy, Anton J.1, Author           
Berndt, Silke1, Author           
Schlögl, Robert1, Author           
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              

Content

show
hide
Free keywords: -
 Abstract: The reactivity of methanol towards oxygenated silver and copper substrates and towards the molecular oxide H4PVMo11O40 has been investigated by a variety of insitu techniques. The intention was to find the chemical origin of the selective action of atomic oxygen and to discuss the influence of the metal species on the oxygen reactivity. The exceptionally high reaction temperature over silver was traced back to the difficulty of forming one active oxygen species. Surface spectroscopies found evidence for three chemically inequivalent atomic oxygen species in the metal-oxygen systems in analogy to the three oxygen forms in the molecular oxide characterized by a single crystal structure analysis. The large body of surface science experiments in these systems has contributed to our understanding of the reaction possibilities but needs to be treated with reservation when a high pressure“ reaction mechanism is considered as these experiments describe only part of the system in the static limit of low chemical potential of the gas phase.

Details

show
hide
Language(s): eng - English
 Dates: 1997
 Publication Status: Issued
 Pages: 20
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0167-2991(97)80973-1
 Degree: -

Event

show
hide
Title: 3rd World Congress on Oxidation Catalaysis
Place of Event: San Diego, USA
Start-/End Date: 1997-09-21 - 1997-09-26

Legal Case

show

Project information

show

Source 1

show
hide
Title: Proceedings of the 3rd World Congress on Oxidation Catalysis
Source Genre: Proceedings
 Creator(s):
Grasselli, R. K., Editor
Oyama, S. T., Editor
Gaffney, A. M., Editor
Lyons, J. E., Editor
Affiliations:
-
Publ. Info: Amsterdam : Elsevier
Pages: 20 Volume / Issue: - Sequence Number: - Start / End Page: 103 - 122 Identifier: ISBN: 978-0-444-82772-2

Source 2

show
hide
Title: Studies in Surface Science and Catalysis
Source Genre: Series
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 110 Sequence Number: - Start / End Page: - Identifier: -