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  Crystal Structures of AlCr2 and MoSi2: Same Structure Type vs. Different Bonding Pattern

Milosavljević, M. D., Burkhardt, U., Moll, P. J. W., König, M., Borrmann, H., & Grin, Y. (2021). Crystal Structures of AlCr2 and MoSi2: Same Structure Type vs. Different Bonding Pattern. Chemistry – A European Journal, 27, 1-9. doi:10.1002/chem.202100817.

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Genre: Journal Article

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 Creators:
Milosavljević, Milica D.1, Author              
Burkhardt, Ulrich2, Author              
Moll, Philip J. W.3, Author              
König, Markus4, Author              
Borrmann, Horst5, Author              
Grin, Yuri6, Author              
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
3Physics of Microstructured Quantum Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_2466701              
4Markus König, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863470              
5Horst Borrmann, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863410              
6Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              

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Free keywords: crystal structure, disorder, focused-ion beam, intermetallic phase, single crystal growth
 Abstract: Abstract In a joint effort utilizing modified sample preparation, microscopy, X-ray diffraction and micro-fabrication, it became possible to prepare single crystals of the ?hidden? phase AlCr2. High-resolution X-ray diffraction analysis is described in detail for two crystals with the similar overall composition, but different degree of disorder, which seems to be the main cause for the differing unit cell parameters. Chemical bonding analysis of AlCr2 in comparison to prototypical MoSi2 shows pronounced differences reflecting the interchange of main group element vs. transition metal as majority component.

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Language(s): eng - English
 Dates: 2021-04-302021-04-30
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1002/chem.202100817
 Degree: -

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Title: Chemistry – A European Journal
  Other : Chem. – Eur. J.
  Other : Chem. Eur. J.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 27 Sequence Number: - Start / End Page: 1 - 9 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058