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  Azine Activation via Silylium Catalysis

Obradors, C., & List, B. (2021). Azine Activation via Silylium Catalysis. Journal of the American Chemical Society, 143(18), 6817-6822. doi:10.1021/jacs.1c03257.

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Azine Activation via Silylium Catalysis.pdf (Publisher version), 832KB
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Azine Activation via Silylium Catalysis.pdf
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 Creators:
Obradors, Carla1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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 Abstract: Practical, efficient, and general methods for the diversification of N-heterocycles have been a recurrent goal in chemical synthesis due to the ubiquitous influence of these motifs within bioactive frameworks. Here, we describe a direct, catalytic, and selective functionalization of azines via silylium activation. Our catalyst design enables mild conditions and a remarkable functional group tolerance in a one-pot setup.

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Language(s): eng - English
 Dates: 2021-03-272021-04-282021-05-12
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/jacs.1c03257
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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 143 (18) Sequence Number: - Start / End Page: 6817 - 6822 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870