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  Perspective on experimental evaluation of adsorption energies at solid/liquid interfaces

Žeradjanin, A. R., Spanos, I., Masa, J., Rohwerder, M., & Schlögl, R. (2021). Perspective on experimental evaluation of adsorption energies at solid/liquid interfaces. Journal of Solid State Electrochemistry, 25(1), 33-42. doi:10.1007/s10008-020-04815-8.

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Perspective on experimental evaluation of adsorption energies at solid_liquid interfaces - s10008-020-04815-8.pdf (Publisher version), 4MB
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Perspective on experimental evaluation of adsorption energies at solid_liquid interfaces - s10008-020-04815-8.pdf
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2020
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 Creators:
Žeradjanin, Aleksandar R.1, Author           
Spanos, Ioannis2, Author           
Masa, Justus2, Author           
Rohwerder, Michael3, Author           
Schlögl, Robert4, 5, Author           
Affiliations:
1Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34–36, 45470 Mülheim an der Ruhr, Germany, ou_persistent22              
2Research Department Schlögl, Max Planck Institute for Chemical Energy Conversion, Max Planck Society, ou_3023874              
3Corrosion, Interface Chemistry and Surface Engineering, Max-Planck-Institut für Eisenforschung GmbH, Max Planck Society, ou_2074315              
4Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
5Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34–36, 45470, Mulheim an der Ruhr, Germany, ou_persistent22              

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 Abstract: Almost 15 years ago, first papers appeared, in which the density functional theory (DFT) was used to predict activity trends of electrocatalytic reactions. That was a major contribution of computational chemistry in building the theory of electrocatalysis. The possibility of computational electrocatalyst design had a massive impact on the way of thinking in modern electrocatalysis. At the same time, substantial criticism towards popular DFT models was developed during the years, due to the oversimplified view on electrified interfaces. Having this in mind, this work proposes an experimental methodology for quantitative description of adsorption energies at solid/liquid interfaces based on the Kelvin probe technique. The introduced approach already gives valuable trends in adsorption energies while in the future should evolve into an additional source of robust values that could complement existing DFT results. The pillars of the new methodology are established and verified experimentally with very promising initial results.

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Language(s): eng - English
 Dates: 2020-08-282020-04-082020-08-302020-09-102021-01
 Publication Status: Published in print
 Pages: 10
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1007/s10008-020-04815-8
 Degree: -

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Title: Journal of Solid State Electrochemistry
  Abbreviation : J. Solid State Electrochem.
Source Genre: Journal
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Publ. Info: Springer-Verlag Germany
Pages: 10 Volume / Issue: 25 (1) Sequence Number: - Start / End Page: 33 - 42 Identifier: ISSN: 1432-8488
CoNE: https://pure.mpg.de/cone/journals/resource/954925623261