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  Bell–like [Ga5] clusters in Sr3Li5Ga5: synthesis, crystal structure and bonding analysis.

Kotsch, M., Prots, Y., Ormeci, A., Senyshyn, A., Kohout, M., & Grin, Y. (2021). Bell–like [Ga5] clusters in Sr3Li5Ga5: synthesis, crystal structure and bonding analysis. Zeitschrift für anorganische und allgemeine Chemie, 647, 1797-1803. doi:10.1002/zaac.202100147.

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 Creators:
Kotsch, Matthias1, Author           
Prots, Yurii2, Author           
Ormeci, Alim1, Author           
Senyshyn, Anatoliy3, Author
Kohout, Miroslav4, Author           
Grin, Yuri5, Author           
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Yuri Prots, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863424              
3External Organizations, ou_persistent22              
4Miroslav Kohout, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863417              
5Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              

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 Abstract: During the search for a possible replacement of the europium in the structure Eu3Li5+xGa5−x (x = 0.15) in order to facilitate the analysis of the chemical bonding in the bell–like [Ga5] clusters, the isostructural compound Sr3Li5Ga5 (space group R (Formula presented.) m, a = 9.6040(5) Å, c = 22.061(1) Å) was discovered. A detailed investigation of the bonding situation in the first five–membered nonconvex Ga cluster utilizing the electron localizability approach became possible, revealing not only first signs of a transition from a Zintl to a Wade cluster, but also the presence of a [Sr6] polycation. © 2021 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH

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Language(s): eng - English
 Dates: 2021-06-022021-06-02
 Publication Status: Published in print
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 Rev. Type: -
 Identifiers: DOI: 10.1002/zaac.202100147
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Title: Zeitschrift für anorganische und allgemeine Chemie
  Other : J. Inorg. Gen Chem.
  Other : Journal of Inorganic and General Chemistry
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: - Volume / Issue: 647 Sequence Number: - Start / End Page: 1797 - 1803 Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895