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  Ionothermal Synthesis of Sulfidobismuth spiro-Dicubane Cations

Knies, M., & Ruck, M. (2021). Ionothermal Synthesis of Sulfidobismuth spiro-Dicubane Cations. ChemistryOpen, 10, 1-6. doi:10.1002/open.202100145.

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 Creators:
Knies, Maximilian1, Author
Ruck, Michael2, Author              
Affiliations:
1External Organizations, ou_persistent22              
2Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

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 Abstract: Bi2S3 was dissolved in the presence of NaCl in the ionic liquid [BMIm]Cl ⋅ 4AlCl3 (BMIm=1-n-butyl-3-methylimidazolium) through annealing the mixture at 180 °C. Upon cooling to room temperature, orange, air-sensitive crystals of Na(Bi7S8)[S(AlCl3)3]2[AlCl4]2 (1) precipitated. X-ray diffraction on single-crystals of 1 revealed a triclinic crystal structure that contains (Bi7S8)5+ spiro-dicubanes, [S(AlCl3)3]2− tetrahedra triples, isolated [AlCl4]− tetrahedra, and sodium cations. © 2021 The Authors. Published by Wiley-VCH GmbH

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Language(s): eng - English
 Dates: 2021-08-132021-08-13
 Publication Status: Published in print
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 Rev. Type: -
 Identifiers: DOI: 10.1002/open.202100145
BibTex Citekey: Knies2021
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Title: ChemistryOpen
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 10 Sequence Number: - Start / End Page: 1 - 6 Identifier: ISSN: 2191-1363
CoNE: https://pure.mpg.de/cone/journals/resource/2191-1363