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  Local adsorption geometry of acetylene on Si(100)(2×1)

Terborg, R., Baumgärtel, P., Lindsay, R., Schaff, O., Gießel, T., Hoeft, J. T., et al. (2000). Local adsorption geometry of acetylene on Si(100)(2×1). Physical Review B, 61(24), 16697-16703. doi:10.1103/PhysRevB.61.16697.

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PhysRevB.61.16697.pdf (Publisher version), 323KB
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PhysRevB.61.16697.pdf
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2000
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APS
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 Creators:
Terborg, Ralf1, Author           
Baumgärtel, Peter1, Author           
Lindsay, Robert1, Author           
Schaff, Oliver1, Author           
Gießel, Tatjana2, Author           
Hoeft, Jon Tobias3, Author           
Polcik, Martin3, Author           
Toomes, R. L.4, Author
Kulkarni, S.1, 5, Author           
Bradshaw, Alexander M.1, Author           
Woodruff, D. P.4, Author
Affiliations:
1Fritz Haber Institute, Max Planck Society, ou_24021              
2Physical Chemistry, Fritz Haber Institute, Max Planck Society, ou_634546              
3Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              
4Department of Physics, University of Warwick, Coventry CV4 7AL, Great Britain, ou_persistent22              
5Physics Department, University of Pune, Poona 411007, Maharashtra, India, ou_persistent22              

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 Abstract: Using C 1s scanned-energy-mode photoelectron diffraction the local adsorption geometry of acetylene on the Si(100)(2x1) surface has been determined and the results are compared with those of a similar study of ethylene adsorption on this surface. Both molecules bond to the surface along the Si-Si dimers with the C-C bonds parallel to the surface such that the C atoms are in off-atop sites relative to the Si dimer atoms. In both cases the Si-Si bond length (2.36±0.21 Å for ethylene and 2.44±0.58 Å for acetylene) is compatible only with the dimer remaining intact after adsorption and not with the Si-Si distance of an ideally terminated undimerized Si(100) surface (3.84 Å).

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Language(s): eng - English
 Dates: 2000-01-132000-06-15
 Publication Status: Issued
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1103/PhysRevB.61.16697
 Degree: -

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Title: Physical Review B
  Abbreviation : Phys. Rev. B
Source Genre: Journal
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Publ. Info: Woodbury, NY : American Physical Society
Pages: 7 Volume / Issue: 61 (24) Sequence Number: - Start / End Page: 16697 - 16703 Identifier: ISSN: 1098-0121
CoNE: https://pure.mpg.de/cone/journals/resource/954925225008