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  Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI)

Albrecht, R., Hoelzel, M., Beccard, H., Rüsing, M., Eng, L., Doert, T., et al. (2021). Potassium Ion Conductivity in the Cubic Labyrinth of a Piezoelectric, Antiferromagnetic Oxoferrate(III) Tellurate(VI). Chemistry – A European Journal, 27, 14299-14306. doi:10.1002/chem.202102464.

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Albrecht, Ralf1, Author
Hoelzel, Markus1, Author
Beccard, Henrik1, Author
Rüsing, Michael1, Author
Eng, Lukas1, Author
Doert, Thomas1, Author
Ruck, Michael2, Author           
Affiliations:
1External Organizations, ou_persistent22              
2Michael Ruck, Max Planck Fellow, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863444              

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 Abstract: Orange-colored crystals of the oxoferrate tellurate K12+6xFe6Te4-xO27 [x=0.222(4)] were synthesized in a potassium hydroxide hydroflux with a molar water-base ratio n(H2O)/n(KOH) of 1.5 starting from Fe(NO3)(3) . 9H(2)O, TeO2 and H2O2 at about 200 degrees C. By using (NH4)(2)TeO4 instead of TeO2, a fine powder consisting of microcrystalline spheres of K12+6xFe6Te4-xO27 was obtained. K12+6xFe6Te4-xO27 crystallizes in the acentric cubic space group I4? 3d. [(FeO5)-O-III] pyramids share their apical atoms in [Fe2O9] groups and two of their edges with [(TeO6)-O-VI] octahedra to form an open framework that consists of two loosely connected, but not interpenetrating, chiral networks. The flexibility of the hinged oxometalate network manifests in a piezoelectric response similar to that of LiNbO3.The potassium cations are mobile in channels that run along the directions and cross in cavities acting as nodes. The ion conductivity of cold-pressed pellets of ball-milled K12+6xFe6Te4-xO27 is 2.3x10(-4) S . cm(-1) at room temperature. Magnetization measurements and neutron diffraction indicate antiferromagnetic coupling in the [Fe2O9] groups.

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Language(s): eng - English
 Dates: 2021-07-282021-07-28
 Publication Status: Issued
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 Rev. Type: -
 Identifiers: ISI: 000693316300001
DOI: 10.1002/chem.202102464
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Title: Chemistry – A European Journal
  Other : Chem. – Eur. J.
  Other : Chem. Eur. J.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 27 Sequence Number: - Start / End Page: 14299 - 14306 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058